Make sure to run all listed commands from the database you are fixing, not from Master.
List the orphaned users in the database
EXEC sp_change_users_login 'Report'
To assign/repair with an existing login:
EXEC sp_change_users_login 'Auto_Fix', 'user'
To create a new login and password for this user, use this instead:
EXEC sp_change_users_login 'Auto_Fix', 'user', 'login', 'password'